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SCH4U Chemistry

Chapter 1: Organic Chemistry: Structure and Properties Beta

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SCH4U Chemistry · 1.3

Esters: physical properties

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Esters: physical properties

  • Esters are polar but have no O–H group, so their molecules cannot hydrogen-bond to each other and they boil lower than alcohols and carboxylic acids of similar size.
  • Small esters dissolve somewhat in water because they can accept hydrogen bonds.
  • Many esters have pleasant fruity smells and are used in flavours and perfumes.
  • An ester boils well below a carboxylic acid of similar size, because the acid's O–H lets its molecules hydrogen-bond to each other.